相变及空位缺陷对高压下GeO_2光学性质的影响

本文采用第一性原理方法,在100 GPa的压力范围内,计算了GeO_2理想晶体和含锗、氧空位点缺陷晶体的光学性质.吸收谱数据表明,压力诱导的三个结构相变对GeO_2晶体的吸收谱均有影响:第一个相变将导致其吸收边蓝移,而第二和第三相变将使得其吸收边红移.锗和氧空位点缺陷的存在将导致GeO_2的吸收边红移,但氧空位点缺陷引起的红移更明显.尽管如此,分析发现,在100 GPa的压力范围内,压力、相变以及空位点缺陷等因素都不会导致GeO_2晶体在可见光区出现光吸收现象(是透明的).波长在532 nm处的折射率数据显示,在GeO_2的四个相区,其折射率均随压力增加而降低;而且,GeO_2的三个结构相变以及锗、氧空位点缺陷都会导致其折射率有所增大.本文预测,GeO_2有成为冲击光学窗口材料的可能.     

里德伯钠原子经绝热快速通道的布居数跃迁相干控制

运用含时多态展开方法和B-样条函数研究了啁啾频率微波场中里德伯钠原子的量子态之间的布居数迁移.计算了里德伯钠原子n=70-77的开普勒频率.计算了在不同的微波场中六个态的布居数从n=70到n=77随时间的迁移,布居数跃迁到最终态n=77达到了98%,这可以通过连续的单光子跃迁来实现.结果表明,通过优化微波脉冲参数可以实现从低态到较高态的布居跃迁的相干控制.     

基于双平行马赫-曾德尔调制器和平衡光电探测器的四倍频可调对称三角形函数波形信号发生器

提出并研究了一种基于双平行马赫-曾德尔调制和平衡光探测的四倍频可调对称三角形函数波形信号发生器.将调制非线性和多参量调控应用到可调对称三角形波形信号的产生中,可实现四倍频信号输出.通过调整调制系数β和时延量τ,可实现光电流表达式向目标函数波形微波信号傅里叶展开式前三项的近似表征,最后得到四倍于射频调制频率的周期性三角形波形信号.结合仿真研究,实现了5 GHz射频调制频率下,20 GHz 三角形波形信号的输出,通过引入拟合误差对所获得的时域波形进行误差估计,所提出的发生器可实现对称系数20％到80％之间的波形输出,且可保证拟合误差小于8％.     

平面波超声成像中的波束合成方法研究进展*

平面波成像通过单次全孔径发射-接收即可获取整幅图像,将成像帧频显著地提升至1000帧/秒以上。然而,平面波成像过程中发射的非聚焦波束将导致回波信号信噪比降低,进而使图像的分辨率和对比度变差。通过多角度相干复合成像技术可以改善平面波成像的图像质量,但是会以牺牲帧频为代价。因此研究人员们开始将新型波束合成技术引入平面波成像中,例如自适应波束合成、基于逆问题求解的波束合成及基于深度学习的波束合成方法等,以期实现图像质量和成像帧频间更好的权衡。该文综述了平面波成像中的新型波束合成方法领域的研究进展,并对该应用进行了总结和展望。     

含损伤黏弹性阻尼加筋层合板声功率和指向性变异*

该文旨在研究损伤位置和程度对自由阻尼加筋层合板声辐射功率和指向性的影响。基于Mindlin和Timoshenko梁理论,建立了自由阻尼层合板-梁组合结构有限元模型。数值求解四边简支边界条件自由阻尼加筋层合板振动响应,继而通过Rayleigh积分计算加筋层合板辐射声功率和指向性。将计算得到的前4阶模态固有频率、声辐射功率与指向性与已有文献进行了对比基本一致,验证了数值模型的正确性。最后,详细讨论了损伤位置和程度对自由阻尼加筋层合板固有频率、振型、声辐射功率和指向性的影响,结果表明：随着结构损伤程度的增大,声辐射功率峰值向低频移动,在更多角度上出现明显的指向性;声辐射功率和指向性对损伤位置比损伤程度更加敏感。     

Improvement on the manipulation of a single nitrogen-vacancy spin and microwave photon at single-quantum level

It remains a great challenge to realize direct manipulation of a nitrogen-vacancy(NV) spin at the single-quantum level with a microwave(MW) cavity. As an alternative, a hybrid system with the spin–phonon–photon triple interactions mediated by a squeezed cantilever-type harmonic resonator is proposed. According to the general mechanical parametric amplification of this in-between phonon mode, the direct spin–phonon and photon–phonon couplings are both exponentially enhanced, which can even further improve the coherent manipulation of a single NV spin and MW photon with a higher efficiency. In view of this triple system with enhanced couplings and the additional sideband adjustable designs, this scheme may provide a more efficient phonon-mediated platform to bridge or manipulate the MW quantum and a single electron spin coherently. It is also hoped to evoke wider applications in the areas of quantum state transfer and preparation,ultrasensitive detection and quantum nondestructive measurement, etc.     

基于双极性混沌序列的托普利兹块状感知矩阵

感知矩阵的构造是压缩感知从理论走向工程应用的关键技术之一.由于托普利兹感知矩阵能够支持快速算法且与离散卷积运算相对应,因此具有重要的研究意义.然而常用的随机托普利兹感知矩阵因其元素的不确定性,使得它在实际应用中受到了诸多约束,例如内存消耗较高和不易于硬件加载.基于此,本文结合双极性混沌序列的内在确定性和托普利兹矩阵的优点,提出了基于双极性混沌序列的托普利兹块状感知矩阵.具体地,首先介绍了双极性混沌序列的产生并分析了它的统计特性.其次,构造了双极性托普利兹块状混沌感知矩阵,从相关性方面证明了新建的感知矩阵具有近乎最优的理论保证,并同时证实了它满足约束等距条件.最后,研究了该感知矩阵针对一维信号和图像的压缩测量效果,并与典型感知矩阵进行了对比.结果表明,提出的感知矩阵对这些测试信号具有更好的测量效果,而且它在内存开销、计算复杂度和硬件实现等方面均具有明显的优势.特别地,该感知矩阵非常适用于多输入-单输出线性时不变系统的压缩感知测量问题.     

Synthesis and Herbicidal Activity of [(Substituted Phenoxyacetoxy) (Substituted Phenyl)Methyl](Methyl) Phosphinates Containing Fluorine

Abstract

A series of [(substituted phenoxyacetoxy)(substituted phenyl)methyl](methyl)phos- phinates containing fluorine were designed and synthesized. All the synthesized compounds were identified by elemental analysis, IR, ¹H NMR, mass spectrometry. O-methyl [(2-fluorophenoxyacetoxy)(2,4-dichlorophenyl)methyl](methyl)phosphinate was further analyzed by X-ray single-crystal diffraction. Their herbicidal activity against a set of weed species was examined. Some of the compounds showed potential herbicidal activity, which provided some indications for further studies on structure modification.

Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file.     

Ultrasensitive electrochemical immunosensor for zeranol detection based on signal amplification strategy of nanoporous gold films and nano-montmorillonite as labels

Nano-montmorillonites belong to aluminosilicate clay minerals with innocuity, high specific surface area, ion exchange, and favorable adsorption property. Due to the excellent properties, montmorillonites can be used as labels for the electrochemical immunosensors. In this study, nano-montmorillonites were converted to sodium montmorillonites (Na-Mont) and further utilized for the immobilization of thionine (TH), horseradish peroxidase (HRP) and the secondary anti-zeranol antibody (Ab₂). The modified particles, Na-Mont-TH-HRP-Ab₂ were used as labels for immunosensors to detect zeranol. This protocol was used to prepare the immunosensor with the primary antibody (Ab₁) immobilized onto the nanoporous gold films (NPG) modified glassy carbon electrode (GCE) surface. Within zeranol concentration range (0.01–12 ng mL⁻¹), a linear calibration plot (Y = 0.4326 + 8.713 X, r = 0.9996) was obtained with a detection limit of 3 pg mL⁻¹ under optimal conditions. The proposed immunosensor showed good reproducibility, selectivity, and stability. This new type of immunosensors with montmorillonites and NPG as labels may provide potential applications for the detection of zeranol.     

Electrochemical separation of uranium and cerium in molten LiCl–KCl

The electrochemical separation of uranium from cerium in LiCl–KCl eutectic and the electrochemical behavior of Ce(III) were studied. According to the cyclic voltammogram of Ce(III) and the former result of U(III), electrodeposition potential was determined at ?1.65 V (vs Ag/AgCl). The uranium metal was successfully deposited and separated from cerium. The morphology of deposit and cross section of electrode were investigated by SEM, firstly uranium deposit alloys with stainless steel and forms a thin transition layer, and secondly the uranium metal layer grows from the transition layer. The separation factors of uranium/cerium on different recovery ratios were determined through a series of steps. It was found that the content of cerium in the deposit and separation factors declined with increasing the initial concentration of U³⁺ in molten salts; the separation factors remained stable at around 20 in different uranium recovery ratios.